170
Practical Hydraulic Systems
The main purpose behind this test is to measure the resistance to oxidation by
measuring the change in the acidity of the oil due to absorbed oxygen. The test procedure
is as follows:
A 300 ml sample of oil is placed in a tube and immersed in an oil bath at 95 °C. Three
liters per hour of oxygen is allowed to pass continuously through the sample for a period
of about 1000 h. The acidity of oil is then measured by determining the neutralization
number.
To measure the neutralization number a weighed amount of a sample of oil is placed in
a beaker. About 100 ml of titration solvent is added to the sample in the beaker. Further
around 30 drops of an indicator is added to this solution. For carrying out the titration
process, standard alcoholic potassium hydroxide is added to the solution drop by drop,
until the color of the solution changes from orange to blue-green. The amount of
potassium hydroxide required in milligrams, indicates the level of oxidation that has
taken place. This is the amount needed to neutralize the acid in one gram of oil.
Rust and corrosion are two altogether different phenomena, although they both
contaminate the oil and promote wear. Rust is the chemical reaction between iron or steel
and oxygen. The presence of moisture in the hydraulic system provides the necessary
oxygen. One primary source of oxygen is the atmospheric air, which enters the reservoir
through the breather cap.
Corrosion on the other hand, is the chemical reaction between a metal and an acid.
Because of rusting or corrosion, the metal surfaces of the hydraulic components are eaten
away. This results in excessive leakage through the affected parts like seals. Rust and
corrosion can be resisted by additives, which form a protective layer on the metal surfaces
and thereby prevent the occurrence of a chemical reaction.
8.4 Neutralization number
The neutralization number is a measure of the relative acidity or alkalinity of a hydraulic
fluid and is specified by the pH level. A fluid having a smaller neutralization number is
recommended, as high-acidity or high-alkaline fluid can cause corrosion of metal parts as
well as a deterioration of seal and packing glands.
For an acidic fluid, the neutralization number equals the number of milligrams (mg) of
potassium hydroxide necessary to neutralize the acid in a 1 g sample. In the case of an
alkaline fluid, the neutralization number equals the amount of alcoholic hydrochloric acid
that is necessary to neutralize the alkali in a 1 g sample of hydraulic fluid. With use,
hydraulic fluid normally has a tendency to become more acidic than basic.
The neutralization number of a hydraulic fluid can be determined by the following test
procedure as illustrated by Figure 8.2.
The oil sample is placed in a titration solution of distilled water, alcohol, toluene and an
indicating agent known as naphthol benzene, which changes color from orange to green
when neutralization occurs.
Alcoholic potassium hydroxide is added from a burette drop by drop, until the solution
changes its color from orange to green. The neutralization number is then calculated
using the following formula,
,. . , Total weight of the titrating solution X 5.61
Neutrahzation number =
Weight of sample used
Hydraulic fluids, which have been treated with additives in order to inhibit the
formation of acids, are usually able to keep this number at a low value of 0 or 0.1.