116 5 Sedimentary rock masses and discontinuities
mudstone, clay minerals occupy 50-90%, with an average of 69.3%.
Among these clay minerals, kaolinite is the essential component, while il-
lite and chlorite are the secondary components. Quartz in the mudstone oc-
cupies 10-30%, with an average of 21.5%.
From the quantitative analyses using the fluorescence spectrum, the
chemical constitution of the mudstone has the following characteristics
(Peng and Meng 2002):
1. The main chemical constitution is SiO
2
, and the secondary is Al
2
O
3
.
In sandy mudstone the content of SiO
2
is up to 65.03%.
2. The contents of ferric oxide (especially Fe
2
O
3
) in granophyric mud-
stone and light gray mudstone are relatively high. The contents of
Fe
2
O
3
in dark and carbonaceous mudstone and dark gray mudstone
are low. Hence the former two mudstones were formed in the oxida-
tion environments, and the latter two were in the deoxidization envi-
ronments.
3. The ignition loss in the immediate roof of coal seam # 13 is rela-
tively high. The main ignited substances include carbon, sulfur, and
other organic substances.
5.3.2 Chemical component effect on mechanical properties
There is a close relationship between the mechanical properties of mud-
stone and its chemical composition, particularly the content of SiO
2
and
ignition loss. Figures 5.11 and 5.12 present the uniaxial compressive
strength and elastic modulus and the content of SiO
2
relationships in a
mudstone sample (Peng and Meng 2002).
It can be seen from Figs. 5.11 and 5.12 that the uniaxial compressive
strength and elastic modulus of mudstone increase as the content of SiO
2
increases. When the content of SiO
2
is less than 40%, the compressive
strength and elastic modulus of mudstone increase slightly. However,
when the content of SiO
2
is greater than 40%, the mechanical strength and
elastic modulus increase significantly as the content of SiO
2
increases. This
is because SiO
2
has a very high uniaxial compressive strength and elastic
modulus. The mechanical properties and the contents of SiO
2
have the fol-
lowing exponential relations:
S
eUCS
025.0
85.6
(5.4)
S
eE
048.0
873.0
(5.5)
where UCS is the uniaxial compressive strength (MPa); S is the content of
SiO
2
(%); E is the elastic modulus (GPa).