derivation of radiation law is made more complex. This seemingly simple concept of
quantized energy had serious implications (not realized then by Planck) and laid the
foundation for the field of quantum mechanics, quantized fields and energies.
Esoteric concepts of probabilities rather than determinism would prevail and
uncertainties in time, space, momentum, energy, and reality itself and aspects of
entanglement of these properties of particles would arise from it. The field of physics
would be totally revolutionized.
A second puzzle was known as the photoelectric effect. Physicists had known for
some time that light, when shone on a charged metal surface like the cathode in a
cathode ray tube, could help liberate electrons to produce a spark. In 1902, Philipp
Lenard found that the effect did not depend on the intensity of the light, but only the
color, or more specifically the frequency. High frequency, blue light created a
bigger spark than low-frequency red light.
In 1905, the young Albert Einstein, then working as a patent clerk, proposed a
simple solution to both these problems. As Planck proposed, the blackbody effect
could be explained if atoms were only allowed to emit or absorb radiation in
discrete units of magnitude hv, where h was Planck’s constant, and v was the
frequency of the radiation. Similarly, Einstein argued that a beam of light of
frequency v consisted of discrete parcels, each with energy hv. The particles were
later given the name photons (in 1926 by Gilbert Lewis). The theo ry explained why
the photoelectric effect worked only below a certain wavelength of the light,
whatever the intensity. A high-frequency, high energy (small wavelength) photon
could knock an electron out of its position in the atom, like a karate expert
shattering a brick with a single blow. A large number of low-frequency photons
had the same effect as a weak person trying to break the brick: what counts is the
power of the punch, not the quantity. In the same year, Einstein further blurred the
definition of matter by showing that energy and mass coul d be converted into one
another, according to the equation E ¼ mc
2
.
Unlike Planck, Einstein, somewhat like Newton, saw the photons as real parti-
cle-like entities, rather than a mathematical abstraction. As he wrote, “Ener gy,
during the propagation of a ray of light, is not continuously distributed over steadily
increasing spaces, but it consists of a finite number of energy quanta localised at
points in space, moving without dividing and capable of being absorbed or
generated only as entities.” Of course, not all of his colleagues were convinced.
The American physicist Robert Millikan also spent 10 years trying to disprove the
quantum theory, through careful study of the photoelectric effect, but only
succeeded in confirming the theory, and obtaining an accurate measurement of
Planck’s constant. (As compensation, he was awarded a Nobel prize for his efforts,
a year after Einstein’s).
In 1912, armed with this new concept of quant ized emission, the Danish
physicist Niels Bohr visited Manchester, where he worked with Rutherford on a
new model of the atom that combined elements of the classical and quantum
approaches. In the Rutherford–Bohr model (Fig. 3.3), electrons circl ed around the
nucleus in orbits as before, but since they cannot lose energy continuously and can
only emit a discrete quantum of radiation, they change orbit (jump) to one with less
The Quantum Jump 21