January 27, 2004 16:17 Elsevier/AID aid
50 2 basic conservation laws
Substituting for pDα/Dt in (2.41) and using c
p
= c
v
+ R, where c
p
(= 1004 J
kg
−1
K
−1
) is the specific heat at constant pressure, we can rewrite the first law of
thermodynamics as
c
p
DT
Dt
− α
Dp
Dt
= J (2.42)
Dividing through by T and again using the equation of state, we obtain the entropy
form of the first law of thermodynamics:
c
p
D ln T
Dt
− R
D ln p
Dt
=
J
T
≡
Ds
Dt
(2.43)
Equation (2.43) gives the rate of change of entropy per unit mass following the
motion for a thermodynamically reversible process. A reversible process is one in
which a system changes its thermodynamic state and then returns to the original
state without changing its surroundings. For such a process the entropy s defined
by (2.43) is a field variable that depends only on the state of the fluid. Thus Ds is
a perfect differential, and Ds/Dt is to be regarded as a total derivative. However,
“heat” is not a field variable, so that the heating rate J is not a total derivative.
2
2.7.1 Potential Temperature
For an ideal gas undergoing an adiabatic process (i.e., a reversible process in which
no heat is exchanged with the surroundings), the first law of thermodynamics can
be written in differential form as
c
p
D ln T − RD ln p = D
c
p
ln T − R ln p
= 0
Integrating this expression from a state at pressure p and temperature T to a state
in which the pressure is p
s
and the temperature is θ, we obtain after taking the
antilogarithm
θ = T
(
p
s
/p
)
R/c
p
(2.44)
This relationship is referred to as Poisson’s equation, and the temperature θ defined
by (2.44) is called the potential temperature. θ is simply the temperature that a
parcel of dry air at pressure p and temperature T would have if it were expanded or
compressed adiabatically to a standard pressure p
s
(usually taken to be 1000 hPa).
Thus, every air parcel has a unique value of potential temperature, and this value
is conserved for dry adiabatic motion. Because synoptic scale motions are approx-
imately adiabatic outside regions of active precipitation, θ is a quasi-conserved
quantity for such motions.
2
For a discussion of entropy and its role in the second law of thermodynamics, see Curry and
Webster (1999), for example.