Григорьев Н.А. Распределение химических элементов в верхней части континентальной коры

Подождите немного. Документ загружается.

Clarke F. The data of geochemistry// U.S. Geol. Surv. Bull., 1924. V. 770. P. 841.

Condie K.C., Wilks M., Rosen D.M., Zlobin V.L. Geochemistry of metasediments from the

Precambrian Harschan Series, eastern Anabar Shield, Siberia // Precambrian Research, 1991. V. 50.

P. 37–47.

Condie K.C., Lee D., Farmer G.L. Tectonic setting and provenance of the Neoproterozoic Uinta

Mountain and Big Cottonwood groups, northern Utah: constrains from geochemistry, Nd isotopes, and

detrial modes // Sedimentary geology, 2001. V. 141–142. P. 443–464.

Condil K.C., Barsky C.K. Origin of qaternary basalts from the black rock Desert Region, Utah //

Geol. Soc. Amer. Bull., 1972. V. 83, No. 2. P. 333–352.

Cooper D.C., Field D. The chemistry and origins of proterozoic low-potash, high-iron

charnockitic gineisses from Tromoy, South Norway // Earth. Plan. Sci, 1981. V. 35, No. 1. P. 171–180.

Davis G.A., Holdwey M.J., Lipman P.W., Romey W.D. Structure, metamorphism and plutonism in

the South-Central Klamath Mountains, California // Geol. Soc. Amer. Bull., 1965. V. 76. No. 8.

P. 933–966.

Di Leo P., Dinelli E., Mondelli G., Schiattarella M. Geology and geochemistry of Jurassis pela-

gic sediments, Scisti silicei Formation, southern Appenines, Italy // Sedimentary geology, 2002.

V. 150. P. 229–246.

El Wardani S.A. On the geochemistry of germanium // Geoch. et Cosmoch. Acta, 1957. V. 13,

No. 1. P. 5–19.

Erikson E.H. Petrology of the composite snoqualmie batholith, Central Cascade Mountains,

Washington // Geol. Soc. Amer. Bull., 1969. V. 80, No. 11. P. 2213–2236.

Ernst W.G. Mineral parageneses in Franciscan metamorphic rocks, Panoche Pass, California //

Geol. Soc. Amer. Bull., 1965. V. 76, No. 8. P. 879–914.

Fairbairn H.W., Ahrens L.N., Gorfinkle L.G. Miner element content of Ontario diabase // Geoch.

et Cosmoch. Acta, 1953. V. 3, No. 1. P. 34–46.

Fisher G.W. Kyanite-, staurolite- and garnet-bearing schists in the Setters Formation, Marylend

Piedmont // Bul. Geol. Soc. Amer., 1971. V. 82, No. 1. ê. 229–232.

Font E., Nedelec A., Trindade R.I.F. et al. Chemostratigraphy of the neoproterozoic mirassol

d'Oeste cap dolostones (Mato Grosso, Brazil): An alternative model for Marinoar cap dolostone for-

mation // Earth and Planetary Science Letters, 2006. V. 250. P. 89–103.

Francalanci L. Trace element partition coefficients forminerals in shoshonitic and calc-alcaline

rocks from Stromboli Island (Aeolion Arc) // Neues Jahrb. fur Mineralogie. Stuttgart, 1989. Bd. 160,

No. 3. S. 229–247.

Gallet S., Jahn B., Van Vliet Lanoﬁ B. et al. Loess geochemistry and its implications for particle

origin and composition of the upper continental crust // Earth and Planetary Science Letters, 1998.

V. 156. P. 157–172.

Goodwin A. M. Archean volcanic studies in the Timmins-Kirkland Lake-Noranda Region of

Ontario and Quebec // Geol. Surv. Bull. of Canada, 1979. No. 278. P. 51.

Götze J. Geochemistry and provenance of the Altendorf feldspathic sandstone in the Middle

Bunter of the Thuringian basin (Germahy) // Chemical geology, 1998. No. 150. P. 43–61.

Grenne T., Roberts D. Geochemistry and volcanic setting of the ordovician forbordfjell and

Jonsvotn Greenstones, trondheim region, Central Norvegian Caledonides // Contrib. to Mineral. and

Petrol., 1980. V. 74, No. 4. P. 375–376.

Griffitts W.R., Oda U. Geochemical prospecting for beryllium // Geol. Surv. Profess. Pap., 1960.

V. 400B. P. 90–93.

Gromet L.P., Dymek R.F., Haskin L.A., Korotev R.L. The North American shale composite. Its

compilation, major and trace element characteristics // Geoch. et Cosmoch. Acta., 1984. V. 48, No. 12.

P. 2469–2482.

Gromet L.P., Silver L.T. Rare earth element distribution among minerals in a granodiorite and their

petrogenetic implications// Geoch. et Cosmoch. Acta., 1983. V. 47, No. 5. P. 925–939.

Hamaguchi H., Kuroda R. Silver content of igneous rocks // Geoch. et Cosmoch. Acta., 1959.

V. 17, No. 1/2. P. 44–52.

Handbook of Geochemistry 11-3. Springer – Verlag Berlin, Heidelberg, New York, 1972.

Handbook of Geochemistry 11-4. Springer – Verlag Berlin, Heidelberg, New York, 1974.

361

Hirst D.M. The geochemistry of modern sediments from the Gulf of Paria-2. The location and dis-

tribution of trace elements// Geoch. et Cosmoch. Acta., 1962. V. 26, No. 11. P. 1147–1187.

Hoffer J.M. Mineralogy and petrology of Santo Tomas black mountain basalt field potrillo vol-

canics, South-Central New Mexico // Geol. Soc. Amer. Bull., 1971. V. 82, No. 3. P. 603–612.

Huber H., Koeberl C., McDonald I, Reimold W.U. Geochemistry and petrology of witwatersrand

and dwyka diamictites from South Africa: Search for an extraterrestrial component // Geoch. et

Cosmoch. Acta, 2001. V. 65, No. 12. P. 2007–2016.

Kalliokoski I. Geology of North-Central Guayana shield, Venezuela // Geol. Soc. Amer. Bull.,

1965. V. 76, No. 9. P. 1027–1050.

Kay S.M., Ardolino A.A., Gorring M.L., Ramos V.A. The somuncura large igneous province in

Patagonia: Interaction of a transient mantle thermal anomaly with a subducting slab // J. of Petrology,

2007. V. 48, No. 1. P. 43–77.

Kobayashi K., Nakamura E. Geochemical evolution of Akagi volcano, NE Japan: Implications for

interaction between island-arc magma and lower crust, and generation of isotopicaly various mag-

mas // J. of Petrology, 2007. V. 42, No. 12. P. 2303–2331.

Kovisars L. Geology of a portion of the North-Central Venesuelan Andes // Geol. Soc. Amer.

Bull., 1971. V. 82, No. 11. P. 3111–3138.

Krienitz M.S., Haase K.M., Mezger K., Shaikh-Mashail M.A. Magma genesis and manthle dyna-

mics at the Hrrat ash samah volcanic field // J. of Petrology, 2007. V. 48, No. 8. P. 1513–1542.

Kuroda R.H., Sandell E.B. Geochemistry molybdenum // Geoch. et Cosmoch. Acta., 1954. V. 6,

No. 1. P. 35–63.

Larsen E.S., Keevil N.B., Harrison H.C. Metod for determining the age of igneous rocks using the

accessory minerals // Geol. Soc. Amer. Bull., 1952. V. 63, No. 10. P. 1045–1052.

Lidden J., Gelinas L., Trudel P. Archean metavolcanics from the Rouyn – Noranda district Abitibi

Greenstone Belt, Quebec. 2. Mobiliti of trace elements and petrogenetic constraints // Can. J. of Earts

Sci., 1982. V. 19, No. 12, P. 2276–2287.

Lipman P.W. Gibson peak pluton: a discordant composite intrusion in the Southeastern Trinity

Alps, Northern California // Geol. Soc. Amer. Bull., 1963. V. 74, No. 10. P. 1259–1280.

Marshesi C., Garrido C., Bosch D. et al. Geochemistry of cretaceous magmatism in Eastern Cuba:

recycling of North American continental sediments and implications for subduction polariby in Greater

Antilles Paleo-arc // J. of Petrology, 2007. V. 48, No. 9. P. 1813–1840.

Maxey L.R. Petrology and Geochemmistry of the beemerville carbonatite – Alkalic Rock

Complex, New Jersey // Geol. Soc. Amer. Bull., 1976. V. 87, No. 11. P. 1551–1559.

Moore G.E. Structure and metamorphism of the Keene-Brattle-boro Area, New Hampshire-

Vermont // Geol. Soc. Amer. Bull., 1949. V. 60, No. 10. P. 1613–1670.

Muramatsu Y., Wedepohl K.H. The Distribution of Iodine in the Earth

s Crust// Geoch. et

Cosmoch. Acta., 1998. V. 147, No. 3–4. P. 201–216 (êÂÙ. ÜÛÌ. «ÉÂÓÎÓ„Ëﬂ», 1999, 2Ç2).

Nessbitt H.W., Yung G.M. Prediction some weathering trends of plutonic and volcanic rocks based

on thermodynamic and kinetic consideration // Geoch. et Cosmoch. Acta., 1984. V. 48. P. 1523.

Osae S., Asiedu D.K., Banoeng-Yakubo B. et al. Provenance and tectonic setting of late protero-

zoic buem sandstones of southeastern Ghana: Evidence from geochemistry and detrital modes // J. of

African Earts Sciences, 2006. No. 44. P. 85–96.

Onishi H., Sandell E.B. Notes on the geochemistry of antimony // Geoch. et Cosmoch. Acta.,

1955. V. 8, No. 4. P. 213–221.

Piller H. Uber Verwitterung sbildung des Brockengranits nordlich st. Andreasberg // Beitrage zur

Mineralogie und Petrographie, 1951. No. 2. S. 498–522.

Pryor W.A. Petrology of the Permian Yellow Sands of Northeastern England and their North Sea

basin equivalents // Sediment. Geol., 1971. V. 6, No. 4. P. 221–254.

Rankama K. On the geochemistry of tantalum // Bull. Com. Geol. Finlande, 1944. No. 133.

ê. 25–32.

Rost F., Grigel W. Über accessorishe Elemente in mitteleuropaischen Eclogiten und ihren

Mineralien // Geoch. et Cosmoch. Acta., 1964. V. 28, No. 12. P. 1933–1951.

Rudnick R.L., Gao S. Composition of the Continental Crust. University of Maryland, College Park,

MD, USA. äÓÏÔ¸˛ÚÂÌ‡ﬂ ‚ÂÒËﬂ, 2004. 64 Ò.

362

Scotford D.M. Metamorphism and axial-plane folding in the Poundridge area, New York // Geol.

Soc. Amer. Bull., 1956. V. 67, No. 9. P. 1155–1198.

Sen N., Nockolds S.R., Allen R. Trace elements in minerals from rocks of the S. California Bato-

lith // Geoch. et Cosmoch. Acta., 1959. V. 16, No. 1/3. P. 58–78.

Shav D.M. The geochemistry of Thalluum // Geoch. et Cosmoch. Acta., 1952. V. 2, No. 2.

P. 118–154.

Shav D.M. The geochemistry of Indium // Geoch. et Cosmoch. Acta., 1952. V. 2, No. 3.

P. 185–206.

Shearer C.K., Papike J.J. Distribution of boron in the Tip Top pegmatite Black Hills, South

Dakota // Geology, 1986. V. 14. No. 2. ê. 119–123.

Sighinolfi G.P. K-Rb ratio in high grade metamorphism; a confirmation of the hypothesis of a con-

tinental crustal evolution // Contr. Miner. and Petrol., 1989. V. 21, No. 4. P. 346–356.

Scotford D.M. Metamorphism and axial-plane folding in the Poundridge Area, New York // Geol.

Soc. Am. Bull., 1956. V. 67, No. 9. P. 1155–1196.

Tilton G.P., Patterson C., Brown H. et al. Isotopic composition and distribution of lead, uranium

and thorium in a precambrian granite// Bull. Geol. Soc. Amer., 1955. V. 66. P. 1131–1148.

Toothill J., Williams C.A., Macdonald R. et al. A Complex Petrogenesis for an Arc Magmatic

Suite, St Kitts, Lesser Antilles // J. of Petrology, 2007. V. 48, No. 1. P. 3–42.

Van de Kamp P.C., Leake B.E. Petrology, geochemistry, provedance and alteration of

Pennsylvanian-Permian Arkose, Colorado and Utah // Geol. Soc. Amer. Bull., 1994. V. 106, No. 12.

P. 1571–1582.

Vincent E., Bilefield L. Cadmium in rocks and minerals from the Scaergaard intrusion, East

Greenland // Geoch. et Cosmoch. Acta, 1966. V. 19. P. 63–59.

Vogt J.H.L. Nickel in Igneous Rocks // Econ. Geol., 1923. V. 18. P. 307–353.

Wedepohl K.H. Geochemie. Berlin: Walter de Gruyter, 1967. 221 s.

Wedepohl K.H. The composition of the continental crust // Geoch. et Cosmoch. Acta., 1995.

V. 59, No. 7. ê. 1217–1232.

Whitney P.R. Variations of the K/Rb ratio in migmatites parageneises of the Northwest

Adirondacks // Geochim. et Cosmochim. Acta., 1984. V. 33. P. 1203–1211.

Wilkinson J.M., Cann J.R. Trace elements and tectonic relationships of basaltic rocks in the

Ballantrae Complex, Ayrshir // Geol. Mag., 1974. V. 3, No. 1. P. 35–41.

Wright N.P. Mineralogic variation in the stone mountain granite, Georgia // Geol. Soc. Amer.

Bull., 1966. V. 77, No. 2. P. 207–210.

Wronkiewicz D.J., Kondie K.S. Geochemistry and mineralogy of sediments from the Ventersdorp

and Transvaal Supergroups, South Africa: Gratonic evolution during the early proterozoic // Geoch. et

Cosmoch. Acta., 1990. V. 54, No. 2. ê. 343–354.

Yang H., Kyser K., Ansdell K. Geochemistry and Nd isotopic compositions of the metasedimenta-

ry rocks in the La Ronge Domain, Trans-Hudson Orogen, Canada: implications for evolution of the

domain // Precambrian Research, 1998. V. 92. P. 37–64.

Yung D.A. Precambrian rocs of the Lake Hopatsong Area, New Jersey // Geol. Soc. Amer. Bull.,

1971. V. 82, No. 1. P. 143–151.

êÖáûåÖ

ê‡ÒÔÂ‰ÂÎÂÌËÂ ıËÏË˜ÂÒÍËı ˝ÎÂÏÂÌÚÓ‚ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ

ÍÓ˚ ÓÔÂ‰ÂÎÂÌÓ ÔÓ ÏÓ‰ÂÎË Ä.Å. êÓÌÓ‚‡ Ò ÒÓ‡‚ÚÓ‡ÏË (1990). ê‡Ò˜ÂÚ ‚˚-

ÔÓÎÌÂÌ ÔÓ ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚Ï ÂÁÛÎ¸Ú‡Ú‡Ï ‡Ì‡ÎËÁÓ‚ ‚‡ÊÌÂÈ¯Ëı „ÓÌ˚ı ÔÓ-

Ó‰, ‚ ÚÓÏ ˜ËÒÎÂ ·ÓÎÂÂ ˜ÂÏ 3400 ÍÓÎË˜ÂÒÚ‚ÂÌÌ˚ı ÏËÌÂ‡ÎÓ„Ë˜ÂÒÍËı ‡Ì‡ÎË-

ÁÓ‚, ÓÔÛ·ÎËÍÓ‚‡ÌÌ˚ı ÔÂËÏÛ˘ÂÒÚ‚ÂÌÌÓ ‚ ëëëê.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ H ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.167%.

71.43% Ï‡ÒÒ H Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç

Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 34.18% ‚ÒÂÈ Ï‡ÒÒ˚ ç, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚

ËÔË‰ÓÎËÚÂ – 14.94, ÍÎËÌÓıÎÓÂ – 5.08, ¯‡ÏÓÁËÚÂ – 3.89, Í‡ÓÎËÌËÚÂ – 2.44,

ÔÂÌÌËÌÂ – 2.27, ÎÓÒÓÌËÚÂ – 1.78, ·ÂÈ‰ÂÎÎËÚÂ – 1.18, Ú˛ËÌ„ËÚÂ – 0.81, ÒÂÔÂÌ-

ÚËÌÂ – 0.68, „ﬁÚËÚÂ – 0.57, ÚÓÏÒÓÌËÚÂ – 0.54.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Li ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚

0.0033%. 61.73% Ï‡ÒÒ Li Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı

ÔÓÓ‰‡ı. ÑÎﬂ Í‡Ê‰ÓÈ „ÓÌÓÈ ÔÓÓ‰˚ ÓÔÂ‰ÂÎÂÌÓ ‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Li

ÔÓ Û˜‡ÒÚÍ‡Ï Ò Â„Ó ÒÓ‰ÂÊ‡ÌËÂÏ, %: ÌËÁÍËÏ (< 0.002), ÒÂ‰ÌËÏ

(0.002–0.005), ÔÓ‚˚¯ÂÌÌ˚Ï (0.005–0.008) Ë ‚˚ÒÓÍËÏ (> 0.008). ê‡ÒÔÂ‰Â-

ÎÂÌËÂ Ï‡ÒÒ Li ‚ ‡ÁÌ˚ı „ÓÌ˚ı ÔÓÓ‰‡ı ÔÓ Ú‡ÍËÏ Û˜‡ÒÚÍ‡Ï ÒÓÓÚ‚ÂÚÒÚ‚ÂÌ-

ÌÓ, %: 0.5–49.8; 33.9–93.2; 3.1–54.4 Ë 0.6–17.5. ìÒÚ‡ÌÓ‚ÎÂÌÓ, ˜ÚÓ ‚ ‚ÂıÌÂÈ

˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ ÎËÚËÂ‚˚ı Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ-

‚‡ÌÓ 8.34% ‚ÒÂÈ Ï‡ÒÒ˚ Li, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ Li-·ËÓÚËÚÂ – 6.9, Li-ÏÛÒÍÓ‚Ë-

ÚÂ – 1.42, ÒÔÓ‰ÛÏÂÌÂ – 0.01, ÎÂÔË‰ÓÎËÚÂ – 0.004, ˆËÌÌ‚‡Î¸‰ËÚÂ – 0.002,

ÔÓÚÓÎËÚËÓÌËÚÂ – 0.0002.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Na ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 2.07%.

66.69% Ï‡ÒÒ H Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌ-

ÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ „‡ÎËÚÂ ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 3.58% ‚ÒÂÈ Ï‡ÒÒ˚ Na.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ä ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 2.23%.

62.35% Ï‡ÒÒ ä Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı

ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 51.92% ‚ÒÂÈ Ï‡ÒÒ˚ ä, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ Í‡ÎËÂ‚˚ı ÔÓÎÂ-

‚˚ı ¯Ô‡Ú‡ı – 51.9, ÒËÎ¸‚ËÌÂ – 0.016, Í‡Ì‡ÎÎËÚÂ – 0.0008.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Rb ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚

0.0098%. ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Rb ‚ „‡ÌËÚ‡ı 0.0205%. 53.54% Ï‡ÒÒ Rb Ì‡ıÓ-

‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Í‡Ê‰ÓÈ „ÓÌÓÈ ÔÓ-

Ó‰Â ÓÔÂ‰ÂÎÂÌÓ ‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Rb ÔÓ Û˜‡ÒÚÍ‡Ï Ò Â„Ó ÒÓ‰ÂÊ‡ÌËÂÏ, %:

ÌËÁÍËÏ (< 0.005), ÒÂ‰ÌËÏ (0.005–0.01), ÔÓ‚˚¯ÂÌÌ˚Ï (0.01–0.03), ‚˚ÒÓÍËÏ

(0.03–0.05) Ë Ó˜ÂÌ¸ ‚˚ÒÓÍËÏ (> 0.05). ê‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Rb ‚ ‡ÁÌ˚ı „Ó-

Ì˚ı ÔÓÓ‰‡ı ÔÓ Ú‡ÍËÏ Û˜‡ÒÚÍ‡Ï ÒÓÓÚ‚ÂÚÒÚ‚ÂÌÌÓ, %: 0.7–76.24; 14.46–79.37;

5.1–47.15; 0–27.23 Ë 0–11.9. ìÒÚ‡ÌÓ‚ÎÂÌÓ, ˜ÚÓ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸-

ÌÓÈ ÍÓ˚ ‚ Û·Ë‰ËÂ‚˚ı Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.3219% ‚ÒÂÈ

Ï‡ÒÒ˚ Rb, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ Rb-·ËÓÚËÚÂ – 0.23, Rb-ÏÛÒÍÓ‚ËÚÂ – 0.091, ÎÂÔË-

‰ÓÎËÚÂ – 0.0008, ÔÓÚÓÎËÚËÓÌËÚÂ – 0.0001.

364

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Cs ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 5.5⋅10

–4

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Cs ‚ „ÎËÌËÒÚ˚ı Ë ÍËÒÎ˚ı ‚ÛÎÍ‡ÌË˜ÂÒÍËı ÔÓÓ‰‡ı –

11.3⋅10

–3

Ë 1.5⋅10

–3

%. 57.79% Ï‡ÒÒ Cs Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓ-

ÙË˜ÂÒÍËı ÔÓÓ‰‡ı. ÑÎﬂ Í‡Ê‰ÓÈ „ÓÌÓÈ ÔÓÓ‰˚ ÓÔÂ‰ÂÎÂÌÓ ‡ÒÔÂ‰ÂÎÂÌËÂ

Ï‡ÒÒ Cs ÔÓ Û˜‡ÒÚÍ‡Ï Ò Â„Ó ÒÓ‰ÂÊ‡ÌËÂÏ, %: ÌËÁÍËÏ (< 5⋅10

–4

), ÒÂ‰ÌËÏ

(5⋅10

–4

–1⋅10

–3

), ÔÓ‚˚¯ÂÌÌ˚Ï (1⋅10

–3

–5⋅10

–3

), ‚˚ÒÓÍËÏ (5⋅10

–3

–1⋅10

–2

) Ë Ó˜ÂÌ¸

‚˚ÒÓÍËÏ (> 1⋅10

–2

). ê‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Cs ‚ ‡ÁÌ˚ı „ÓÌ˚ı ÔÓÓ‰‡ı ÔÓ Ú‡-

ÍËÏ Û˜‡ÒÚÍ‡Ï ÒÓÓÚ‚ÂÚÒÚ‚ÂÌÌÓ, %: 2.28–75.15; 6.32–56.41; 11.42–85.6; 0–25.46

Ë 0–26.26%. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ ˆÂÁËÂ‚˚ı Ï‡ÍÒËÏËÌÂ-

‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.243% ‚ÒÂÈ Ï‡ÒÒ˚ Cs, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ Cs-·ËÓÚË-

ÚÂ – 0.2, ·ÂËÎÎÂ – 0.02, Cs-ÒÚÂÍÎÂ – 0.018, ÎÂÔË‰ÓÎËÚÂ – 0.004, ÔÓÚÓÎËÚËÓ-

ÌËÚÂ – 0.001.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ÇÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 2.3⋅10

–4

59.63% Ï‡ÒÒ ÇÂ Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. ÑÎﬂ Í‡Ê‰ÓÈ „ÓÌÓÈ

ÔÓÓ‰˚ ÓÔÂ‰ÂÎÂÌÓ ‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Be ÔÓ Û˜‡ÒÚÍ‡Ï Ò Â„Ó ÒÓ‰ÂÊ‡ÌË-

ÂÏ, %: ÌËÁÍËÏ (< 1⋅10

–4

), ÒÂ‰ÌËÏ (1⋅10

–4

–4⋅10

–4

), ÔÓ‚˚¯ÂÌÌ˚Ï (4⋅10

–4

–1⋅10

–3

)

Ë ‚˚ÒÓÍËÏ (> 1⋅10

–3

). ê‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Be ‚ ‡ÁÌ˚ı „ÓÌ˚ı ÔÓÓ‰‡ı ÔÓ

Ú‡ÍËÏ Û˜‡ÒÚÍ‡Ï ÒÓÓÚ‚ÂÚÒÚ‚ÂÌÌÓ, %: 3.58–55.66; 10.46–59.22; 1.6–46.34;

0–27.95. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ ·ÂËÎÎËÂ‚˚ı ÏËÌÂ‡Î‡ı

ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 1.29% ‚ÒÂÈ Ï‡ÒÒ˚ Be, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ·ÂËÎÎÂ – 0.65,

ÙÂÌ‡ÍËÚÂ – 0.2, ·ÂÚ‡Ì‰ËÚÂ – 0.17, ıËÁÓ·ÂËÎÎÂ – 0.11, „ÂÎ¸‚ËÌÂ – 0.1, „‡-

‰ÓÎËÌËÚÂ – 0.06, ·ÂıÓËÚÂ < 0.01.

Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ÒÂ‰ÌËÂ ÒÓ‰ÂÊ‡ÌËﬂ, %: Mg –

1.77, Ca – 3.89. ÅÓÎ¸¯Â ÔÓÎÓ‚ËÌ˚ Ëı Ï‡ÒÒ ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡-

‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı: Mg – 59.33, Ca – 66.84%. ìÒÚ‡ÌÓ‚ÎÂÌÓ ÒÎÂ‰Û-

˛˘ÂÂ ‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Mg ÔÓ ÏËÌÂ‡Î‡Ï, %: ‚ ÌÂÏ‡„ÌËÂ‚˚ı – 7.65, Ï‡„-

ÌËÂ‚˚ı – 93.13. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 5.85% Ï‡ÒÒ Mg (‚ ÔÂÌ-

ÌËÌÂ – 3.22, ÒÂÔÂÌÚËÌÂ – 1.05, ÓÎË‚ËÌÂ – 0.54, ˝ÌÒÚ‡ÚËÚÂ – 0.52, Ï‡„ÌÂÁËÚÂ –

0.24, ÙÓÒÚÂËÚÂ – 0.22, ÍÎËÌÓ„ÛÏËÚÂ – 0.03, „ÛÏËÚÂ – 0.02, ·ÛÒËÚÂ – 0.01).

ê‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ˚ ë‡ ÔÓ ÏËÌÂ‡Î‡Ï, %: ‚ Í‡Î¸ˆËÂ‚˚ı – 94.97, ÌÂÍ‡Î¸ˆË-

Â‚˚ı – 3.38. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 39.21% Ï‡ÒÒ ë‡, ‚ ÚÓÏ

˜ËÒÎÂ: ‚ Í‡Î¸ˆËÚÂ – 37.5, ‡Ô‡ÚËÚÂ – 1.32, ‡‡„ÓÌËÚÂ – 0.36, ÙÎ˛ÓËÚÂ – 0.03.

Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ÒÂ‰ÌËÂ ÒÓ‰ÂÊ‡ÌËﬂ, %: Sr –

0.027, Ba – 0.051. ÅÓÎ¸¯Â ÔÓÎÓ‚ËÌ˚ Ëı Ï‡ÒÒ ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙË-

˜ÂÒÍËı ÔÓÓ‰‡ı, %: Sr – 61.53, Ba – 64.08%. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸-

ÌÓÈ ÍÓ˚ ‚ Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ: Sr – 0.4% (‚ ˆÂÎÂÒÚËÌÂ –

0.26, ·‡ËÚÂ – 0.14); Ba – 0.99% (‚ ·‡ËÚÂ – 0.72, „ÓÎÎ‡Ì‰ËÚÂ – 0.15, ÔÒËÎÓ-

ÏÂÎ‡ÌÂ – 0.07, ˆÂÎÂÒÚËÌÂ – 0.05).

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Ç ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.0034%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ B ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı –

0.0072 Ë 0.0034%. 77.37% Ï‡ÒÒ B Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË-

˜ÂÒÍËı ÔÓÓ‰‡ı, ‚ ÍÓÚÓ˚ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 4.08% Â„Ó Ï‡ÒÒ, ‚ ÚÓÏ ˜ËÒÎÂ,

%: ‚ ÚÛÏ‡ÎËÌÂ – 3.91, ÍÓÌÂÛÔËÌÂ – 0.16, ‡ÍÒËÌËÚÂ – 0.01%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Al ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 7.61%.

51.88% Ï‡ÒÒ Al Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı, ‰Îﬂ

Í‡Ê‰ÓÈ ËÁ ÍÓÚÓ˚ı ÓÔÂ‰ÂÎÂÌÓ ‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Al ÔÓ Û˜‡ÒÚÍ‡Ï Ò Â„Ó ÒÓ-

‰ÂÊ‡ÌËÂÏ, %: ÌËÁÍËÏ (< 5.3), ÔÂÓ·Î‡‰‡˛˘ËÏ (5.3–10.6), ÔÓ‚˚¯ÂÌÌ˚Ï

365

(10.6–15.87) Ë ‚˚ÒÓÍËÏ (> 15.87). å‡ÒÒ˚ Al ‡ÒÔÂ‰ÂÎÂÌ˚ ‚ ˝ÚËı Û˜‡ÒÚÍ‡ı ÒÓ-

ÓÚ‚ÂÚÒÚ‚ÂÌÌÓ, %: 2.22–26.5; 71.5–75.59; 0.97–15.61 Ë 0–8. ÄÎ˛ÏËÌËÂ‚˚Â Ï‡Í-

ÒËÏËÌÂ‡Î˚ Ì‡ıÓ‰ﬂÚÒﬂ ÔÂËÏÛ˘ÂÒÚ‚ÂÌÌÓ ‚ Û˜‡ÒÚÍ‡ı Ò ÔÂÓ·Î‡‰‡˛˘ËÏ ÔÓ-

‚˚¯ÂÌÌ˚Ï Ë ‚˚ÒÓÍËÏ ÒÓ‰ÂÊ‡ÌËÂÏ Al. ìÒÚ‡ÌÓ‚ÎÂÌÓ, ˜ÚÓ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË

ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ ‡Î˛ÏËÌËÂ‚˚ı Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ

2.66% ‚ÒÂÈ Ï‡ÒÒ˚ Al, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÒËÎÎËÏ‡ÌËÚÂ – 1.33, ‰Ë‡ÒÔÓÂ – 0.33,

‡Ì‰‡ÎÛÁËÚÂ – 0.27, „Ë··ÒËÚÂ – 0.19, ÒÚ‡‚ÓÎËÚÂ – 0.19, ·ÂÏËÚÂ – 0.11, ¯ÔËÌÂ-

ÎË – 0.11, ‰ËÒÚÂÌÂ – 0.09, ÍÓÛÌ‰Â – 0.03, Ò‡ÔÙËËÌÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ C ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.81%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ C ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı 2.87 Ë

0.62%. 97.59% Ï‡ÒÒ C Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ-

‰‡ı. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ÔÓ˜ÚË ‚Òﬂ Ï‡ÒÒ‡ ë ÒÍÓÌˆÂÌÚË-

Ó‚‡Ì‡ ‚ ÒÓ·ÒÚ‚ÂÌÌ˚ı ÏËÌÂ‡Î‡ı Ë Ó„‡ÌË˜ÂÒÍËı ‚Â˘ÂÒÚ‚‡ı, ‚ ÚÓÏ ˜ËÒÎÂ, %:

‚ „‡ÙËÚÂ – 14.8, Ó„‡ÌË˜ÂÒÍËı ‚Â˘ÂÒÚ‚‡ı – 12.58.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Si ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 28.32%.

65.11% Ï‡ÒÒ Si Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı

ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 41.45% Ï‡ÒÒ˚ Si, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ Í‚‡ˆÂ – 39.54, ÓÔ‡-

ÎÂ – 1.91.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Ge ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 1.3⋅10

–4

59.62% Ï‡ÒÒ Ge Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Sn ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 3.5⋅10

–4

71.29% Ï‡ÒÒ Sn Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌ-

ÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.66% Ï‡ÒÒ˚ Sn ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ ‚ Í‡ÒÒËÚÂËÚÂ.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Pb ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.0017%.

69.79% Ï‡ÒÒ Pb Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı

ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 1.02% Ï‡ÒÒ˚ Pb, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ „‡ÎÂÌËÚÂ – 0.97, ˆÂÛÒ-

ÒËÚÂ – 0.03, ‡Ì„ÎÂÁËÚÂ – 0.01, Ò‚ËÌˆÂ Ò‡ÏÓÓ‰ÌÓÏ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ N ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.0106%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ N ‚ ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰‡ı 0.042%, ‚ ÍÓÚÓ˚ı ÒÍÓÌˆÂÌÚË-

Ó‚‡ÌÓ 79.59% Â„Ó Ï‡ÒÒ.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ P ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ – 0.069%.

60.51% Ï‡ÒÒ P Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç ÙÓÒÙ‡Ú‡ı ÒÍÓÌˆÂÌ-

ÚËÓ‚‡ÌÓ 35.67% Ï‡ÒÒ ê, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ‡Ô‡ÚËÚÂ – 33.54, Í‡·ÓÌ‡Ú-‡Ô‡ÚË-

ÚÂ – 1.89, ÏÓÌ‡ˆËÚÂ – 0.23, ÍÒÂÌÓÚËÏÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ As ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 5.6⋅10

–4

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ As ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı 7.7⋅10

–4

Ë 9.2⋅10

–4

%, ‚ ÍÓÚÓ˚ı Ì‡ıÓ‰ËÚÒﬂ 84.44% Â„Ó Ï‡ÒÒ. ìÒÚ‡ÌÓ‚ÎÂÌÓ, ˜ÚÓ ‚ Ï˚¯¸-

ﬂÍÓ‚˚ı ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 1.61% Ï‡ÒÒ˚ As, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ‡ÒÂ-

ÌÓÔËËÚÂ – 0.71, ÌËÍÂÎËÌÂ – 0.5, „ÂÒ‰ÓÙËÚÂ – 0.24, ‡ÛËÔË„ÏÂÌÚÂ – 0.09, ÍÓ-

·‡Î¸ÚËÌÂ – 0.07.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Sb ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 8.1⋅10

–5

73.77% Ï‡ÒÒ Sb Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç

ÒÛ¸ÏﬂÌ˚ı ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.059% Ï‡ÒÒ Sb, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÔË-

‡„ËËÚÂ – 0.02, ÚÂÚ‡˝‰ËÚÂ – 0.017, ÙÂÈ·Â„ËÚÂ – 0.01, ÒÚÂÙ‡ÌËÚÂ – 0.007,

‡ÌÚËÏÓÌËÚÂ – 0.004, ‰ÊÂÏÒÓÌËÚÂ – 0.001.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Bi ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 2.9⋅10

–5

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Bi ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı 2.6⋅10

–5

366

Ë 5.4⋅10

–5

%, ‚ ÍÓÚÓ˚ı Ì‡ıÓ‰ËÚÒﬂ 82.59% Â„Ó Ï‡ÒÒ. Ç ‚ËÒÏÛÚÓ‚˚ı ÏËÌÂ‡Î‡ı

ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.74% Ï‡ÒÒ Bi, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ·ËÒÏÛÚËÚÂ – 0.31, ‚ËÒÏÛÚË-

ÌÂ – 0.25, ‚ËÒÏÛÚÂ Ò‡ÏÓÓ‰ÌÓÏ – 0.15, ÚÂÚ‡‰ËÏËÚÂ – 0.03.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ é ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 47.87%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ é ‚ ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰‡ı 48.51%. 55.24% Ï‡ÒÒ é Ì‡ıÓ-

‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ S ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.14%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ S ‚ ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰‡ı 0.36%. Ç ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂ-

Ú‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ 74.3% ‚ÒÂÈ Ï‡ÒÒ˚ S, ËÏÂ˛˘ÂÈÒﬂ ‚

‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡-

ÌÓ 43.47% Ï‡ÒÒ S, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÔËËÚÂ – 24.08, ÔËÓÚËÌÂ – 7.98, ‡Ì„Ë‰-

ËÚÂ – 7.49, „ËÔÒÂ – 3.1, Ï‡Í‡ÁËÚÂ – 0.46, ÍËÁÂËÚÂ – 0.11, ·‡ËÚÂ – 0.07, ÒÂ-

Â Ò‡ÏÓÓ‰ÌÓÈ – 0.06, ﬂÓÁËÚÂ – 0.04, ı‡Î¸ÍÓÔËËÚÂ – 0.03, ˆÂÎÂÒÚËÌÂ Ë ÔÂÌÚ-

Î‡Ì‰ËÚÂ – ÔÓ 0.02, ÒÙ‡ÎÂËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Se ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 1.5⋅10

–5

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Se ‚ ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰‡ı 2.7⋅10

–5

%. Ç ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡-

ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ 78.01% ‚ÒÂÈ Ï‡ÒÒ˚ Se. Ç Ï‡ÍÒËÏË-

ÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.0011% Ï‡ÒÒ Se, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ‚ËÒÏÛÚËÌÂ –

0.0009 Ë ÍËÌÓ‚‡Ë – 0.0002%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ F ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.051%,

ÒÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ F ‚ ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰‡ı 0.047%. 60.05% Ï‡ÒÒ F Ì‡ıÓ‰ËÚ-

Òﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚

ÒÓ·ÒÚ‚ÂÌÌ˚ı ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 7.3% Ï‡ÒÒ F, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚

‡Ô‡ÚËÚÂ – 4.84, ÙÎ˛ÓËÚÂ – 2.08, ÚÓÔ‡ÁÂ – 0.18, „ÛÏËÚÂ – 0.08, ÍÎËÌÓ„ÛÏËÚÂ –

0.07, ·‡ÒÚÌÂÁËÚÂ – 0.05.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Cl ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.15%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Cl ‚ ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰‡ı – 0.65%, ‚ ÍÓÚÓ˚ı ÒÍÓÌˆÂÌÚ-

ËÓ‚‡ÌÓ 87.64% Ï‡ÒÒ Cl. Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ ÒÓ·ÒÚ-

‚ÂÌÌ˚ı ÏËÌÂ‡Î‡ı Ì‡ıÓ‰ËÚÒﬂ 73.04% Ï‡ÒÒ Cl, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ „‡ÎËÚÂ –

72.58, ÒËÎ¸‚ËÌÂ – 0.21, ÒÍ‡ÔÓÎËÚÂ – 0.19, Í‡Ì‡ÎÎËÚÂ – 0.05, ·Ë¯ÓÙËÚÂ – 0.01,

ÒÓ‰‡ÎËÚÂ – < 0.01%.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Cu ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚

0.0039%. 70.8% Ï‡ÒÒ Cu ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç ‚Âı-

ÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ ÏÂ‰Ì˚ı ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ

1.186% Ï‡ÒÒ Cu, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ı‡Î¸ÍÓÔËËÚÂ – 0.975, ÍÓ‚ÂÎÎËÌÂ – 0.06,

·ÓÌËÚÂ – 0.036, ‡ÁÛËÚÂ – 0.035, ÍÛ·‡ÌËÚÂ – 0.035, Ï‡Î‡ıËÚÂ – 0.029, ÏÂ‰Ë Ò‡-

ÏÓÓ‰ÌÓÈ – 0.011, ı‡Î¸ÍÓÁËÌÂ – 0.004, ·ÎÂÍÎ˚ı Û‰‡ı – 0.001.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Ag ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 1.1⋅10

–5

62.36 % Ï‡ÒÒ Ag Ì‡ıÓ‰ËÚÒﬂ ‚ ÓÒ‡‰Ó˜Ì˚ı Ë Ô‡‡ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı.

ÑÎﬂ Í‡Ê‰ÓÈ ËÁ „ÓÌ˚ı ÔÓÓ‰ ÓÔÂ‰ÂÎÂÌÓ ‡ÒÔÂ‰ÂÎÂÌËÂ Ï‡ÒÒ Ag ÔÓ Û˜‡-

ÒÚÍ‡Ï Ò Â„Ó ÒÓ‰ÂÊ‡ÌËÂÏ, %: ÌËÁÍËÏ (< 6⋅10

–6

), ÒÂ‰ÌËÏ (6⋅10

–6

–1.8⋅10

–5

ÔÓ‚˚¯ÂÌÌ˚Ï (1.8⋅10

–5

–1.62⋅10

–4

) Ë ‚˚ÒÓÍËÏ (1.62⋅10

–4

–4.86⋅10

–4

). ê‡ÒÔÂ-

‰ÂÎÂÌËÂ Ï‡ÒÒ Ag ‚ ‡ÁÌ˚ı „ÓÌ˚ı ÔÓÓ‰‡ı ÔÓ Ú‡ÍËÏ Û˜‡ÒÚÍ‡Ï ÒÓÓÚ‚ÂÚÒÚ-

‚ÂÌÌÓ, %: 4.81–33.04; 13.94–46.81; 28.8–69.89; 0–33.22. èÂ‰ÔÓÎ‡„‡ÂÚ-

Òﬂ, ˜ÚÓ ‚ Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 2.62% ‚ÒÂÈ Ï‡ÒÒ˚ Ag, ‚ ÚÓÏ

˜ËÒÎÂ, %: ‚ ÒÂÂ·Â Ò‡ÏÓÓ‰ÌÓÏ – 0.99, ‡„ÂÌÚËÚÂ – 0.56, ÔË‡„ËËÚÂ –

0.4, ‡Í‡ÌÚËÚÂ – 0.31, ÒÚÂÙ‡ÌËÚÂ – 0.22, ÙÂÈ·Â„ËÚÂ – 0.07, ıÎÓ‡„ËË-

367

ÚÂ – 0.03, ÁÓÎÓÚÂ Ò‡ÏÓÓ‰ÌÓÏ – 0.02, ÏÂ‰Ë Ò‡ÏÓÓ‰ÌÓÈ – 0.01, ÚÂÚ‡˝‰Ë-

ÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Au ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚

4.36⋅1⋅10

–7

%, 97.4% Ï‡ÒÒ ÍÓÚÓÓÈ ÔÂ‰ÒÚ‡‚ÎÂÌÓ „ÓÌ˚ÏË ÔÓÓ‰‡ÏË Ò ÒÓ‰Â-

Ê‡ÌËÂÏ Au < 1⋅10

–6

%. Ç ÌËı Ì‡ıÓ‰ËÚÒﬂ 73.5% Ï‡ÒÒ Au. éÍÓÎÓ 2.6% Ï‡ÒÒ˚

ÍÓÌÚËÌÂÌÚ‡Î¸Ì˚ı ÔÓÓ‰ ËÏÂÂÚ ÒÓ‰ÂÊ‡ÌËÂ Au 1⋅10

–6

–5⋅10

–5

%. Ç ÌËı ÒÍÓÌ-

ˆÂÌÚËÓ‚‡ÌÓ 23.4% Ï‡ÒÒ Au. ëÓ‰ÂÊ‡ÌËÂÏ Au 5⋅10

–5

–5⋅10

–3

%, ÒÓÓÚ‚ÂÚÒÚ‚Û-

˛˘ËÏ ÔÓÏ˚¯ÎÂÌÌ˚Ï Ë ÔÓÚÂÌˆË‡Î¸ÌÓ ÔÓÏ˚¯ÎÂÌÌ˚Ï Û‰‡Ï, ı‡‡ÍÚÂË-

ÁÛÂÚÒﬂ ÓÍÓÎÓ 0.01% Ï‡ÒÒ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚. á‰ÂÒ¸ ÒÍÓÌ-

ˆÂÌÚËÓ‚‡ÌÓ 3.1% Ï‡ÒÒ Au. ê‡ÒÔÂ‰ÂÎÂÌËÂ Au ‚ ÒÓ‚ÓÍÛÔÌÓÒÚË ÍÓÌÚËÌÂÌ-

Ú‡Î¸Ì˚ı ÔÓÓ‰ ÔÓ˜ÚË, ÔÓÔÓˆËÓÌ‡Î¸ÌÓÂ Ëı Ï‡ÒÒ‡Ï, Ô‡ÍÚË˜ÂÒÍË ÒÓÓÚ‚ÂÚ-

ÒÚ‚ÛÂÚ „ÂÓıËÏË˜ÂÒÍÓÏÛ ·‡Î‡ÌÒÛ. ÉÎ‡‚Ì˚Â ÌÓÒËÚÂÎË Au – ÏÂÚ‡ÏÓÙË˜ÂÒÍËÂ

ÔÓÓ‰˚. á‡‚ËÒËÏÓÒÚ¸ ÒÂ‰ÌÂ„Ó ÒÓ‰ÂÊ‡ÌËﬂ Au ÓÚ ÒÓÒÚ‡‚‡ „ÓÌ˚ı ÔÓÓ‰ ‚˚-

‡ÊÂÌ‡ ÒÎ‡·Ó. Ç Ò‡ÏÓÓ‰ÌÓÏ ÁÓÎÓÚÂ ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 4.1–4.6% Ï‡ÒÒ˚ Au,

ËÏÂ˛˘ÂÈÒﬂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚.

Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ÒÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ, %: Zn –

0.0075%, Cd – 6.4⋅10

–5

%, Hg – 6.5⋅10

–6

%. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ-

‰ËÚÒﬂ 68.38% Ï‡ÒÒ Zn, 66.04 Ï‡ÒÒ Cd Ë 67.54% Ï‡ÒÒ Hg. Ç ÒÙ‡ÎÂËÚÂ ÒÍÓÌˆÂÌ-

ÚËÓ‚‡ÌÓ 0.31% ‚ÒÂÈ Ï‡ÒÒ˚ Zn Ë 0.32% ‚ÒÂÈ Ï‡ÒÒ˚ Cd. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı

ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.771% ‚ÒÂÈ Ï‡ÒÒ˚ Hg, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÍËÌÓ‚‡Ë –

0.757, ÏÂÚ‡ˆËÌÌ‡·‡ËÚÂ – 0.01, ·ÎÂÍÎ˚ı Û‰‡ı – 0.003, Â‡Î¸„‡Â – 0.001.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Sc –

0.0016, Y – 0.0026 Ë La – 0.0032. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ‰ËÚÒﬂ, %:

71.98 Ï‡ÒÒ Sc, 51.7 Ï‡ÒÒ Y, 59.5 Ï‡ÒÒ La. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ-

‚‡ÌÓ 4.25% Ï‡ÒÒ Y, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 1.85, ÏÓÌ‡ˆËÚÂ – 1.45, ÍÒÂÌÓ-

ÚËÏÂ – 0.69, ËÚÚË‡ÎËÚÂ – 0.14, „‡‰ÓÎËÌËÚÂ – 0.06, ˝‚ÍÒÂÌËÚÂ – 0.03, ÙÂ„Û-

ÒÓÌËÚÂ – 0.02, ·ÎÓÏÒÚ‡Ì‰ËÌÂ – 0.01. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ

12.69% Ï‡ÒÒ La, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 6, ÏÓÌ‡ˆËÚÂ – 5.28, ·‡ÒÚÌÂÁËÚÂ –

1.4, „‡‰ÓÎËÌËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Ce –

0.0063 Ë Pr – 8.7⋅10

–4

. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ‰ËÚÒﬂ: 66.3% Ï‡ÒÒ Ce,

71.7% Ï‡ÒÒ Pr. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 11.96% Ï‡ÒÒ Ce, ‚ ÚÓÏ

˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 5.64, ÏÓÌ‡ˆËÚÂ – 5.06, ·‡ÒÚÌÂÁËÚÂ – 1.26; 12.06% Ï‡ÒÒ Pr,

‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÏÓÌ‡ˆËÚÂ – 5.98, ÓÚËÚÂ – 4.86, ·‡ÒÚÌÂÁËÚÂ – 1.21, „‡‰ÓÎË-

ÌËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Nd –

0.0029, Sm – 5.7⋅10

–4

. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ‰ËÚÒﬂ 68.1% Ï‡ÒÒ Nd

Ë 60.3 Ï‡ÒÒ Sm. B Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 9.13% Ï‡ÒÒ Nd, ‚ ÚÓÏ

˜ËÒÎÂ, %: ‚ ÏÓÌ‡ˆËÚÂ – 5.38, ÓÚËÚÂ – 3.48, ·‡ÒÚÌÂÁËÚÂ – 0.25, ËÚÚË‡ÎËÚÂ –

0.01, „‡‰ÓÎËÌËÚÂ – 0.01%; 7.43% Ï‡ÒÒ Sm, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÏÓÌ‡ˆËÚÂ – 3.88,

ÓÚËÚÂ – 3.2, ·‡ÒÚÌÂÁËÚÂ – 0.28, ËÚÚË‡ÎËÚÂ – 0.03, „‡‰ÓÎËÌËÚÂ – 0.02, ˝‚ÍÒÂ-

ÌËÚÂ 0.01, ÙÂ„ÛÒÓÌËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Eu –

1.3⋅10

–4

, Gd – 6.3⋅10

–4

. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ‰ËÚÒﬂ: 67.46% Ï‡ÒÒ

Eu Ë 70.93 Ï‡ÒÒ Gd. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 1.87% Ï‡ÒÒ Eu, ‚

ÚÓÏ ˜ËÒÎÂ, %: ‚ ÏÓÌ‡ˆËÚÂ – 0.9, ÓÚËÚÂ – 0.7, ·‡ÒÚÌÂÁËÚÂ – 0.25, ËÚÚË‡ÎËÚÂ –

0.01, ÙÂ„ÛÒÓÌËÚÂ – 0.01; 4.24% Ï‡ÒÒ Gd, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÏÓÌ‡ˆËÚÂ – 2.48,

368

ÓÚËÚÂ – 1.45, ÍÒÂÌÓÚËÏÂ – 0.13, ·‡ÒÚÌÂÁËÚÂ – 0.1, ËÚÚË‡ÎËÚÂ – 0.05, „‡‰ÓÎË-

ÌËÚÂ – 0.01, ˝‚ÍÒÂÌËÚÂ 0.01, ÙÂ„ÛÒÓÌËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Tb –

8.9⋅10

–5

, Dy – 4.8⋅10

–4

. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ‰ËÚÒﬂ 64.3% Ï‡ÒÒ Tb

Ë 68.2 Ï‡ÒÒ Dy. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 9.71% Ï‡ÒÒ Tb, ‚ ÚÓÏ

˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 7.01, ÏÓÌ‡ˆËÚÂ – 2.34, ÍÒÂÌÓÚËÏÂ – 0.21, ËÚÚË‡ÎËÚÂ –

0.1, ÙÂ„ÛÒÓÌËÚÂ – 0.02, „‡‰ÓÎËÌËÚÂ – 0.02, ˝‚ÍÒÂÌËÚÂ – 0.01; 5.42% Ï‡ÒÒ Dy,

‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 4.5, ÏÓÌ‡ˆËÚÂ – 0.43, ÍÒÂÌÓÚËÏÂ – 0.29, ËÚÚË‡ÎË-

ÚÂ – 0.14, ÙÂ„ÛÒÓÌËÚÂ – 0.03, ˝‚ÍÒÂÌËÚÂ 0.02, „‡‰ÓÎËÌËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Ho –

1.3⋅10

–4

, Er – 2.7⋅10

–4

. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ‰ËÚÒﬂ 68.19% Ï‡ÒÒ Ho

Ë 68% Ï‡ÒÒ Er. Ç Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 4.43% Ï‡ÒÒ Ho, ‚ ÚÓÏ

˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 3.32, ÍÒÂÌÓÚËÏÂ – 0.89, ËÚÚË‡ÎËÚÂ – 0.1, ·‡ÒÚÌÂÁËÚÂ –

0.05, ˝‚ÍÒÂÌËÚÂ – 0.03, ÙÂ„ÛÒÓÌËÚÂ – 0.02, „‡‰ÓÎËÌËÚÂ – 0.02; 4.51% Ï‡ÒÒ Er,

‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 3.73, ÍÒÂÌÓÚËÏÂ – 0.47, ËÚÚË‡ÎËÚÂ – 0.18, ÙÂ„Û-

ÒÓÌËÚÂ – 0.06, ˝‚ÍÒÂÌËÚÂ – 0.04, „‡‰ÓÎËÌËÚÂ – 0.01, ·ÎÓÏÒÚ‡Ì‰ËÌÂ – 0.01, ˜Â‚-

ÍËÌËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Yb –

2.5⋅10

–4

, Lu – 4.8⋅10

–5

. Ç ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı Ì‡ıÓ‰ËÚÒﬂ: 61.1% Ï‡ÒÒ Yb

Ë 59.2% Ï‡ÒÒ Lu. B Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 6.47% Ï‡ÒÒ Yb, ‚ ÚÓÏ

˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 5.74, ÍÒÂÌÓÚËÏÂ – 0.34, ËÚÚË‡ÎËÚÂ – 0.26, ˝‚ÍÒÂÌËÚÂ –

0.06, ÙÂ„ÛÒÓÌËÚÂ – 0.05, „‡‰ÓÎËÌËÚÂ – 0.01, ·ÎÓÏÒÚ‡Ì‰ËÌÂ – 0.01; 6.87%

Ï‡ÒÒ Lu, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÓÚËÚÂ – 6, ÍÒÂÌÓÚËÏÂ – 0.58, ËÚÚË‡ÎËÚÂ – 0.2,

ÙÂ„ÛÒÓÌËÚÂ – 0.06, ˝‚ÍÒÂÌËÚÂ – 0.03.

Ç ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ÒÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ, %: Th –

9.1⋅10

–4

, U – 2.5⋅10

–4

. 56.2% Ï‡ÒÒ Th Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı,

56% Ï‡ÒÒ U – ‚ ÓÒ‡‰Ó˜Ì˚ı ÔÓÓ‰‡ı Ë ÔÓ‰ÛÍÚ‡ı Ëı ÏÂÚ‡ÏÓÙËÁÏ‡. Ç Ï‡ÍÒË-

ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 17.47% Ï‡ÒÒ Th, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÏÓÌ‡ˆËÚÂ –

8.29, ÓÚËÚÂ – 5.8, ÚÓËÚÂ – 3.08, ËÚÚË‡ÎËÚÂ – 0.14, Û‡ÌËÌËÚÂ – 0.02, ÍÒÂÌÓ-

ÚËÏÂ – 0.12, ÙÂ„˛ÒÓÌËÚÂ – 0.01, ˝‚ÍÒÂÌËÚÂ – 0.01; 5.72% Ï‡ÒÒ U, ‚ ÚÓÏ ˜ËÒ-

ÎÂ, %: ‚ ÓÚËÚÂ – 2.11, Û‡ÌËÌËÚÂ – 1.83, ÏÓÌ‡ˆËÚÂ – 1.4, ˝‚ÍÒÂÌËÚÂ – 0.15, ËÚ-

ÚË‡ÎËÚÂ – 0.11, ÙÂ„˛ÒÓÌËÚÂ – 0.02, ÚÓËÚÂ – 0.08, ˆËÚÓÎËÚÂ – 0.01, ·ÎÓÏ-

ÒÚ‡Ì‰ËÌÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Ti ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.39%.

67.25% Ï‡ÒÒ Ti Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç ÚËÚ‡ÌÓ‚˚ı ÏËÌÂ-

‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 30.07% Ï‡ÒÒ Ti, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ËÎ¸ÏÂÌËÚÂ – 14.2,

Ti-Ï‡„ÌÂÚËÚÂ – 1.96, ÚËÚ‡ÌËÚÂ – 11.1, ÛÚËÎÂ – 1.62, ÎÂÈÍÓÍÒÂÌÂ – 0.92, ‡Ì‡Ú‡-

ÁÂ – 0.27.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Zr –

0.016 Ë Hf – 4.5⋅10

–4

. Ç ˆËÍÓÌÂ ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 28.4% Ï‡ÒÒ Zr Ë 24%

Ï‡ÒÒ Hf.

CÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ V ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.0121%.

71.99% V Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Ti-Ï‡„ÌÂÚËÚÂ ÒÍÓÌˆÂÌÚ-

ËÓ‚‡ÌÓ 1.3% Ï‡ÒÒ V.

CÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚, %: Nb –

0.0012, í‡ – 0.00014. 61.35% Ï‡ÒÒ Nb Ë 54.44% Ï‡ÒÒ Ta Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓ-

ÙË˜ÂÒÍËı ÔÓÓ‰‡ı. ìÒÚ‡ÌÓ‚ÎÂÌÓ, ˜ÚÓ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ-

369

˚ ‚ ÌËÓ·ËÂ‚˚ı ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.71% Ï‡ÒÒ Nb, ‚ ÚÓÏ ˜ËÒÎÂ,

%: ‚ ËÎ¸ÏÂÌÓÛÚËÎÂ – 0.26, ÍÓÎÛÏ·ËÚÂ – 0.26, ˝‚ÍÒÂÌËÚÂ – 0.09, ÙÂ„ÛÒÓÌË-

ÚÂ – 0.06, ÔËÓıÎÓÂ – 0.03, ·ÎÓÏÒÚ‡Ì‰ËÌÂ – 0.01. Ç ÌËÓ·ËÂ‚˚ı Ë Ú‡ÌÚ‡ÎÓ-

‚˚ı ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 1.58% Ï‡ÒÒ í‡, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ËÎ¸ÏÂ-

ÌÓÛÚËÎÂ – 0.8, ÍÓÎÛÏ·ËÚÂ – 0.34, ˝‚ÍÒÂÌËÚÂ – 0.28, ÔËÓıÎÓÂ – 0.02, Ú‡ÌÚ‡-

ÎËÚÂ – 0.1, ÙÂ„ÛÒÓÌËÚÂ – 0.02, ·ÎÓÏÒÚ‡Ì‰ËÌÂ – 0.02.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Cr ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚

0.0092%. 74.72% Ï‡ÒÒ Cr Ì‡ıÓ‰ËÚÒﬂ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç ıÓÏ-

¯ÔËÌÂÎË‰‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.64% Ï‡ÒÒ Cr.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ åÓ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚

1.56⋅10

–4

%. 65.7% Ï‡ÒÒ åÓ ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç

Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 4.64% Ï‡ÒÒ åÓ, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ¯ÂÂ-

ÎËÚÂ – 0.14, ÔÓ‚ÂÎÎËÚÂ – 0.01, ÏÓÎË·‰ÂÌËÚÂ – 4.49.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ W ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 2.03⋅10

–4

65.7% ‚ÒÂÈ Ï‡ÒÒ˚ W ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Ï‡ÍÒË-

ÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 2.23% Ï‡ÒÒ W, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ‚ÓÎ¸Ù‡ÏËÚÂ

– 0.23, ¯ÂÂÎËÚÂ – 2.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Mn ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.077 %.

64.28 % Ï‡ÒÒ Mn ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. èÂ‰ÔÓÎ‡-

„‡ÂÚÒﬂ, ˜ÚÓ ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ ‚ Ï‡„‡ÌˆÂ‚˚ı ÏËÌÂ‡-

Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 7.02% ‚ÒÂÈ Ï‡ÒÒ˚ Mn, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ·‡ÛÌËÚÂ –

1.8, ÚÂÙÓËÚÂ – 0.98, „‡ÛÒÏ‡ÌËÚÂ – 0.93, ÒÔÂÒÒ‡ÚËÌÂ – 0.73, Ó‰ÓıÓÁËÚÂ –

0.63, ÔËÓÎ˛ÁËÚÂ – 0.43, „ÓÎÎ‡Ì‰ËÚÂ – 0.41, ÍÛÚÌ‡„ÓËÚÂ – 0.31, ÔÒËÎÓÏÂÎ‡-

ÌÂ – 0.2, ÍËÔÚÓÏÂÎ‡ÌÂ – 0.14, Ï‡Ì„‡ÌËÚÂ – 0.12, Ó‰ÓÌËÚÂ – 0.12, Mn-Í‡Î¸ˆË-

ÚÂ – 0.07, ﬂÍÓ·ÒËÚÂ – 0.07, ÚÓ‰ÓÓÍËÚÂ – 0.06, ‚ÂÌ‡‰ËÚÂ – 0.02.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Fe ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ – 4.06%.

67.08 Ï‡ÒÒ Fe ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Ï‡ÍÒËÏËÌÂ‡-

Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 20.46% Ï‡ÒÒ Fe, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ Ï‡„ÌÂÚËÚÂ – 11.5,

ËÎ¸ÏÂÌËÚÂ – 1.76, ÒË‰ÂËÚÂ – 1.35, „ÂÏ‡ÚËÚÂ – 1.35, „ÂÚËÚÂ – 1.31, Ú˛ËÌ„Ë-

ÚÂ – 1.06, Ti-Ï‡„ÌÂÚËÚÂ – 0.91, ÔËËÚÂ – 0.73, ÔËÓÚËÌÂ – 0.44, Ù‡ﬂÎËÚÂ –

0.05, Ï‡Í‡ÁËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Co ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚

0.0017%. 71.47% Ï‡ÒÒ ëÓ ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç

Ï‡ÍÒËÏËÌÂ‡Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.28% Ï‡ÒÒ Co, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ „ÓÎÎ‡Ì-

‰ËÚÂ – 0.14, ÔÒËÎÓÏÂÎ‡ÌÂ – 0.05, ÔÂÌÚÎ‡Ì‰ËÚÂ – 0.05, ÍÓ·‡Î¸ÚËÌÂ – 0.02, ‚ËÓ-

Î‡ËÚÂ – 0.01, ‡ÒÂÌÓÔËËÚÂ – 0.01.

ëÂ‰ÌÂÂ ÒÓ‰ÂÊ‡ÌËÂ Ni ‚ ‚ÂıÌÂÈ ˜‡ÒÚË ÍÓÌÚËÌÂÌÚ‡Î¸ÌÓÈ ÍÓ˚ 0.005%.

71.75 Ï‡ÒÒ Ni ÒÓÒÂ‰ÓÚÓ˜ÂÌÓ ‚ ÏÂÚ‡ÏÓÙË˜ÂÒÍËı ÔÓÓ‰‡ı. Ç Ï‡ÍÒËÏËÌÂ‡-

Î‡ı ÒÍÓÌˆÂÌÚËÓ‚‡ÌÓ 0.88% Ï‡ÒÒ Ni, ‚ ÚÓÏ ˜ËÒÎÂ, %: ‚ ÔÂÌÚÎ‡Ì‰ËÚÂ – 0.58,

„‡ÌËÂËÚÂ – 0.11, ‚‡˝ÒËÚÂ – 0.07, ‚ËÓÎ‡ËÚÂ – 0.06, ÌËÍÂÎËÌÂ – 0.04, „ÂÒ‰Ó-

ÙËÚÂ – 0.02.