3.2 Fluid description of a plasma 55
which is a general form of the Navier–Stokes equation. If temperature differences
across the fluid are not too large, µ may be treated as constant giving
ρ
Du
Dt
= ρF −∇ P + µ
∇
2
u +
1
3
∇(∇ · u)
(3.16)
Assuming for the moment that F is given, it is clear that, whichever of these
forms of the equation of motion may be appropriate, we need at least one more
equation for P. We may anticipate that this will be provided by consideration
of energy conservation and indeed it is. But this alone does not close the set of
equations; closure is achieved by means of the relations of classical thermodynam-
ics. There are two reasons why we need the thermodynamic relations. In the first
place energy balance introduces the internal energy of the fluid element and this
is a thermodynamic variable; it depends on the thermodynamic state of the fluid.
Secondly, in addition to the coefficient of viscosity appearing in the momentum
equation, energy balance brings in more transport coefficients and these, too, are
functions of the state variables such as ρ and T .
There is any number of state variables, each of which has its particular use, but
experiments have established empirically that for fluids in equilibrium all thermo-
dynamic properties can be expressed in terms of any two state variables. We shall
take P and ρ as the two independent variables so that every other state variable is
then expressed as a function of these two by means of an equation of state. Thus
our set of equations will be closed by the energy equation (for P) plus as many
equations of state as there are state variables (other than ρ and P) appearing in the
transport coefficients or elsewhere in the energy equation.
Fluids in motion are clearly not in equilibrium. Nevertheless, it has been found
that classical thermodynamics may be applied to non-equilibrium states provided
that the fluid passes through a series of quasi-static equilibrium states. Then if
P and ρ, say, are given by their instantaneous values all the other state variables
can be defined in terms of these two by their equations of state. In order that a
quasi-static equilibrium be established we assume that changes in the macroscopic
variables take place on a time scale long compared with the relaxation time for the
attainment of local equilibrium.
The first law of thermodynamics is a statement of energy conservation in that it
equates the change in the internal energy per unit mass E between two equilibrium
states to the sum of the increase in heat energy per unit mass and the work done
per unit mass on the system, that is
dE = dQ + dW (3.17)
Note that E is a state variable so that dE depends only on the initial and final states
and not on the manner in which the change in internal energy is brought about. On