
183 Atmospheric remote sounding from the ground
From equations (7.14) and (7.15) we get
L
ν
=
˜
L
ν∞
e
−k
ν
m
0
sec θ
;
likewise at another frequency ν
but at the same solar zenith angle,
L
ν
=
˜
L
ν
∞
e
−k
ν
m
0
sec θ
.
Therefore, after division and taking logarithms,
ln
L
ν
L
ν
= ln
˜
L
ν∞
˜
L
ν
∞
+ (k
ν
− k
ν
)m
0
sec θ. (7.16)
The technique used in measuring column ozone is to choose two frequencies in the ultra-
violet, one with weak ozone absorption (small k
ν
) and one with strong absorption (large
k
ν
), and carry out measurements at several zenith angles. Then, if the left-hand side of
equation (7.16) is plotted against sec θ , a set of points close to a straight line is found. The
slope of the line of best fit is (k
ν
− k
ν
)m
0
and, if the extinction coefficients are known,
the total mass of absorber (ozone in this case) in a vertical column is obtained. From this
the column ozone is readily found.
Dobson exploited this idea in his ozone spectrophotometer, developed during the 1920s
and 1930s, using simple but effective experimental techniques, including a null method for
measuring L
ν
/L
ν
. Essentially the same instrument is still used world-wide for monitoring
amounts of column ozone, and it was from a long series of observations with such an
instrument that the Antarctic ozone hole was discovered; see Section 6.7.
7.3.2 Radars
Radars employed for atmospheric observation measure the backscatter of pulses of radio
waves. Weather radars utilise backscattering of radio waves (with wavelengths of a few
centimetres) from water drops and ice crystals in the troposphere to estimate precipitation
rates, thus providing important data for weather forecasting systems. In the lower and mid-
dle atmosphere, backscattering of waves with a wavelength of a metre or so can take place
from inhomogeneities in the atmospheric refractive index N for radio propagation. These
inhomogeneities may, for example, be due to fluctuations of temperature and humidity
associated with patches of turbulence, stratification of atmospheric properties in thin layers
and regions of ionisation (including ionisation due to meteor trails). The length scales of
inhomogeneities that give rise to strong scattering are of the order of half the radio wave-
length or greater.
3
In this section we shall focus on backscattering from inhomogeneities
in N , rather than from precipitation.
3
Compare with Bragg X-ray diffraction from crystals, for which constructive interference occurs when 2d sin θ =
nλ,whered is the interplanar spacing, θ is the grazing angle, λ is the wavelength and n ≥ 1isaninteger.From
this equation it f ollows that d ≥ λ/2. For radar scattering we have a similar formula except that d is interpreted
as the length scale of the inhomogeneities in N .