regular gasoline in cold-start conditions. It pro-
duces reduced carbon dioxide compared with
regular gas.
Oxygenate To treat, combine, or infuse with
oxygen.
Oxygenates Substances which, when added
to gasoline, increase the amount of oxygen in
the gasoline blend. Ethanol, methyl tertiary
butyl ether (MTBE), ethyl tertiary butyl ether
(ETBE), and methanol are common oxygenates.
Additives to gasoline reduce its carbon dioxide
emissions.
Ozone (O
3
) A major air pollutant, ozone gas is
a triatomic form of oxygen. It is not usually
emitted directly into the air, but at ground level
it is created by a chemical reaction between
oxides of nitrogen (NO
x
) and volatile organic
compounds (VOC) in the presence of sunlight.
Ozone has the same chemical structure whe-
ther it occurs miles above the Earth or at ground
level. It is produced in two layers: the tropo-
sphere or ground-layer ozone, known as “bad”
ozone; and the stratosphere or upper ozone,
known as “good” ozone.
Ozone is a primary constituent of smog.
Motor vehicle exhaust and industrial emissions,
gasoline vapors, and chemical solvents, as well
as natural sources, emit NO
x
and VOC that help
form ozone. Sunlight and hot weather cause
ground-level ozone to form in harmful con-
centrations in the air. As a result, it is known as
a summertime air pollutant. Ozone occurs in
both urban and rural areas. It is considered a
significant health risk, particularly for children
with asthma. It also damages crops, trees, and
other vegetation.
Ozone is produced naturally in the stratosphere.
“Good” ozone occurs naturally in the strato-
sphere approximately 10–30 miles (16–48 km)
above the Earth’s surface, and forms a layer that
protects life on Earth from the Sun’s harmful
ultraviolet (UV) rays. This natural shield has gradu-
ally been damaged or depleted by human-made
chemicals including chlorofluorocarbons (CFCs),
hydrochlorofluorocarbons (HCFCs), halons, methyl
bromide, carbon tetrachloride, and methyl chloro-
form, all known as ozone-depleting substances.
Even though there has been a reduction in
the use of many ozone-depleting substances,
their use in the past can still affect the protective
ozone layer. Research indicates that depletion
of the “good” ozone layer is being reduced
worldwide. Thinning of the protective ozone
layer can be observed using satellite measure-
ments, particularly over the polar regions.
Ozone depletion can cause increased amounts
of UV radiation to reach the Earth, which can
lead to more cases of skin cancer, cataracts, and
impaired immune systems. Measures are being
taken to reduce ozone emissions in the USA
through the Clean Air Act, and also in other
countries. See also:
Air pollutants; ozone-depleting
substance
Ozone-depleting substance (ODS) Family of
human-made compounds that have been shown
to deplete stratospheric ozone. ODS include
chlorofluorocarbons (CFCs), bromofluorocarbons
(halons), methyl chloroform, carbon tetrachloride,
methyl bromide, and hydrochlorofluorocarbons
(HCFCs). Once released into the air, these ozone-
depleting substances degrade very slowly. They
can remain intact for years as they move through
the troposphere until they reach the stratosphere.
There they are broken down by the intensity of
the Sun’s ultraviolet rays and release chlorine
and bromine molecules, which destroy the “good”
ozone. Scientists estimate that one chlorine atom
can destroy 100,000 “good” ozone molecules.
See also:
Ozone
Ozone hole Thin place in the ozone layer in
the stratosphere. Thinning of the stratospheric
ozone has been linked to the destruction of stra-
tospheric ozone by chlorofluorocarbons (CFCs)
170 Oxygenate