4.1 Application of Lean Flames in Internal Combustion Engines 305
are not spherical, measurements by combined Mie and LIF [173] may be possible.
In very dense s prays, it may be that so-called ‘ballistic imaging’ can provide some of
the information required [174]. Although many of these techniques can, and have,
been used in engines, optical access to the spray in the engine may be too limited in
some circumstances, or it may be desirable to measure the spray in isolation from
the engine to investigate the fundamental physics of atomisation, evaporation, and
mixing – but at realistic pressures and temperatures. For these two reasons, basic
research on sprays is being performed in high-pressure, high-temperature cells, or
rapid-compression machines (e.g., [175–177]), which give the best possible optical
access to measure spray formation, evaporation, entrainment, rates of mixture for-
mation, ignition, and soot formation. Spray break-up length can be measured in such
environments by the technique described in [178].
A particularly interesting technique is the simultaneous visualisation of the fuel
in the liquid and vapour phases by use of spectral separation of the exciplex LIF
the liquid phase from the gas-phase fluorescence: Exciplex fluorescence results from
two tracers that combine in the liquid phase only to form an exci
ted comlplex).Re-
cently, fully quantitative planar measurements have been reported in evaporating
fuel sprays under conditions of pressure and temperature relevant to engines [179],
based on full characterisation of the temperature dependence of the particular exci-
plex system used.
The measurement of the mixing of fuel vapour is usually idealised by the fa-
miliar technique of using a non-fluorescing fuel, which does not fluoresce by itself,
with the addition of a fluorescing tracer (the technique called planar laser-induced
fluorescence, PLIF), which has an evaporation rate, matched as far as possible, to
that of the fuel [180]. This technique is being extended in a number of ways. Recently,
publications have begun to appear that attempt to distinguish between various frac-
tions of a gasoline fuel, e.g. [181], and quantitative, high-temporal-resolution PLIF
[182] has been developed. Measurements of the 3D distribution of vapour have been
technically possible for some time [183], although the technique will remain expen-
sive. The fuel vapour from a diesel spray is similarly measured by a non-fluorescing
fuel ‘doped’ with a fluorescent tracer: Here, the tracers have a higher boiling point
than those used for gasoline. For diesel sprays, under certain conditions, Rayleigh
scattering has also been used to measure fuel-vapour density: Experimentally, laser
flare must be kept as low as possible with this delicate technique. So-called filtered
Rayleigh scattering avoids flare because the only wavelength detected is that which
is Doppler shifted by Brownian motion, the elastically scattered light from stationary
surfaces being filtered out [184, 185].
To measure the fuel-vapour concentration, its temperature, or the equivalence
ratio, recent developments use the general dependence of the PLIF tracer signal on
both temperature and oxygen partial pressure by making two simultaneous mea-
surements: See [186] for simultaneous measurements of temperature and residual
gas concentration based on acetone laser-induced fluorescence. When toluene is
used for temperature measurements of the gas phase, this approach has the great
convenience of needing but a single excitation wavelength [187 ]. An alternative
technique for the measurement of fuel vapour is based on the relative extinction
of two wavelengths by the vapour phase and by the liquid droplets [188] although,
because this is a line-of-sight technique, it relies on an assumption of axisymmetry