g11.4
Use of the Equations of Change to Solve Steady-State Problems
349
Adiabatic Frictionless
Processes in
an
Ideal
Gas
To determine that function, we have to make experimental measurements or solve Eqs.
11.4-44 to 49. In 1881, Lorenz3 obtained an approximate solution to these equations and found
C
=
0.548. Later, more refined calculations4 gave the following dependence of
C
on Pr:
Pr 0.73 (air)
1
10
100 1000
C
0.518 0.535
0.620 0.653 0.665 0.670
These values of
C
are nearly in exact agreement with the best experimental measurements in
the laminar flow range (i.e., for GrPr
<
lo9h5
Develop equations for the relationship of local pressure to density or temperature in a stream
of ideal gas in which the momentum flux
.r
and the heat flux
q
are negligible.
SOLUTION
With
7
and
q
neglected, the equation of energy [Eq.
(1)
in Table 11.4-11 may be rewritten as
For an ideal gas,
=
RT/M, where M is the molecular weight of the gas, and Eq. 11.4-52
becomes
Dividing this equation by
p
and assuming the molar heat capacity
$
=
MS
to be constant,
we can again use the ideal gas law to get
Hence the quantity in parentheses is a constant along the path of a fluid element, as is its an-
tilogarithm, so that we have
TC,/R
1
=
p
constant
(1
1.4-55)
This relation applies to all thermodynamic states
p,
T
that a fluid element encounters as it
moves along with the fluid.
Introducing the definition
y
=
tp/Pv
and the ideal gas relations
$
-
Sv
=
R and
p
=
pRT/M, one obtains the related expressions
p'y-l"y~-'
=
constant
(1
1.4-56)
and
pp-Y
=
constant
(1
1.4-57)
These last three equations find frequent use in the study of frictionless adiabatic processes in
ideal gas dynamics. Equation 11.4-57 is
a
famous relation well worth remembering.
L. Lorenz,
Wiedemann's Ann. der Physik u. Chemie,
13,42247,582406 (1881). See also
U.
Grigull,
Die Grundgesetze der Warrneiibertragung,
Springer-Verlag, Berlin, 3rd edition (1955), pp. 263-269.
%ee
S.
Whitaker,
Fundamental Principles
of
Heat Transfer,
Krieger, Malabar Fla. (1977), g5.11. The
limiting case of Pr
+
w
has been worked out numerically by E.
J.
LeFevre [Heat Div. Paper 113, Dept.
Sci. and Ind. Res., Mech. Engr. Lab. (Great Britain), Aug. 19561 and it was found that
Equation 11.4-51a corresponds to the value
C
=
0.670 above.
This
result has been verified experimentally
by
C.
R.
Wilke,
C.
W. Tobias, and
M.
Eisenberg,
J.
Electrochem. Soc.,
100,513-523 (1953), for the analogous
mass transfer problem.
For
an
analysis of free convection in three-dimensional creeping flow, see W.
E.
Stewart,
Int.
J.
Heat
and Mass Transfer,
14,1013-1031 (1971).