Sawyer D. Oxygen Chemistry

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размер 8.56 МБ
добавлен 30 апреля 2011 г.

Oxford University Press. 1991. 236 p.
Introduction: Why oxygen chemstry?
Redox thermodynamics for oxygen species (03, O2, HOO-, O2-, HOOH, HOO-, O, O-, and HQ-); effects of media and pH
Nature of chemical bonds for oxygen in its compounds
Reactivity of Hydrogen Peroxide, Alkyl Hydroperoxides, and Peracids
Reactivity of oxygen radicals [HO, RO-, HOO-, ROO-, and RC(O)O-]
Reactivity of dioxygen and its activation for selective dioxygenation, mono-oxygenation, dehydrogenation, and auto-oxidation of organic substrates and metals (corrosion)
Reactivity of superoxide ion
Reactivity of oxy-anions [HO', RO', HOO' (ROO~), and O2--] as nucleophiles and one-electron reducing agents

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