Wiley. 2004. 380 p.
In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of mode synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an inteational authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry.
Contents
Preface
Introduction
Hydrogenation and Transfer Hydrogenation
Oxidation Reactions
Carbon–Carbon Bond Formations via Ruthenacycle Intermediates
Carbon–Carbon Bond Formation via p-Allylruthenium Intermediates
Ruthenium-Catalyzed Olefin Metathesis
Ruthenium-Catalyzed Cyclopropanation
Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates
Ruthenium-Catalyzed Reactions via sp C–H, sp2 C–H, sp3 C–H, and C–Halogen Bond Activations
Ruthenium Lewis Acid-Catalyzed Reactions
Ruthenium-Catalyzed Reactions with CO and CO2
Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes
Ruthenium-Promoted Radical Reactions
Ruthenium-Catalyzed Bond Cleavage Reactions
Index
In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of mode synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an inteational authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry.
Contents
Preface
Introduction
Hydrogenation and Transfer Hydrogenation
Oxidation Reactions
Carbon–Carbon Bond Formations via Ruthenacycle Intermediates
Carbon–Carbon Bond Formation via p-Allylruthenium Intermediates
Ruthenium-Catalyzed Olefin Metathesis
Ruthenium-Catalyzed Cyclopropanation
Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates
Ruthenium-Catalyzed Reactions via sp C–H, sp2 C–H, sp3 C–H, and C–Halogen Bond Activations
Ruthenium Lewis Acid-Catalyzed Reactions
Ruthenium-Catalyzed Reactions with CO and CO2
Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes
Ruthenium-Promoted Radical Reactions
Ruthenium-Catalyzed Bond Cleavage Reactions
Index